As hinted at in my previous post , there is a new project underway that uses the Zmanim API in a way that I had never really imagined. Using the Smack API, Michael Kopinsky created the ZmanimBot that allows getting zmanim by instant messaging the ZmanimBot, an internet bot. It currently supports the Google Talk IM system, but support for other systems might follow. Please be aware that the system is under development and is not always up. Additional information can be found on the ZmanimBot page.
Update (ג׳ אייר תשע״ג April 13, 2008): The ZmanimBot is now available via AIM